Optimisation of process parameters using response surface methodology to improve the liquid fraction yield from pyrolysis of water hyacinth.

The water hyacinth has been identified as a persistent threat to the pillars of sustainability, resulting in an increased demand for cost-effective mitigation measures. Existing control measures such as chemical and mechanical methods have proved ineffective and expensive, although their use in a biorefinery is deemed sustainable. The study focused on using the response surface methodology of Design-Expert to optimise process parameters, emphasising temperature and particle size, to improve the liquid fraction yield from the pyrolysis of water hyacinths. The experiment was conducted in the temperature range of 273.22 and 676.78 °C, with a particle size range of 380 and 2620 µm, and subjected to a heating rate of 30 °C/min and a nitrogen flow rate of 25 l/min. The results suggest that an increase in temperature and particle size led to a rise in the liquid fraction and a decrease in char. The liquid fraction increased from 24.36 wt.% at 273.22 °C to 48.45 wt.% at 575 °C and reduced to 25.56 wt.% at 626.78 °C. Char decreased from 58.21 to 33.84 wt.% at 626.78 °C. Given this, the quadratic model was found fit for optimisation. Statistical analysis of variance showed good agreement between actual data and the predicted model. This study argues that the valorisation of water hyacinths, if accompanied by policies and strategies, can trigger comprehensive socio-economic and environmental benefits by implementing optimum conditions to generate an improved liquid fraction that tends to influence its commercialisation. It is envisaged that the study's findings will inform policy discussions and formulation.

Spatio-Temporal Patterns and Consequences of Road Kills: A Review.

The development and expansion of road networks have profoundly impacted the natural landscape and various life forms. Animals are affected by these roads in a myriad of ways, none as devastating as road mortalities. This article reviews the literature on the magnitude, spatiotemporal patterns, factors, and consequences of Animal-Vehicle Collisions (AVCs) and the subsequent road kills. Furthermore, the review paper briefly outlines the relationship between roads and animals in the surrounding landscape and later examines the nature and impacts of AVCs. This article evaluates the statistics on the number of road kills and a critical analysis of the spatiotemporal patterns of these mortalities is also evaluated. Subsequently, the review paper examines current mitigation measures and the challenges impeding their success. The paper then concludes with an evaluation of geospatial tools (GIS) and other technologies used in road kill studies. The relevant findings of this paper are that, (1) factors influencing road kill patterns interact with one another; (2) AVCs have serious environmental, economic and social consequences; (3) road kill mitigation strategies suffer several challenges hindering their success; and (4) specific geospatial tools and other technologies have been utilised in assessing AVC road kill patterns. The review, therefore, recommends including overall road kill clusters of all animals in mortality surveys, increasing the spatial coverage of road kill observations, consistent surveying, sufficient research on nighttime driving distances and speed, utilising citizen science in all road mortality studies and incorporating GIS into all apps used for recording road kills. An increased sufficiency in road kill data coupled with improved technologies can enable more effective mitigation strategies to prevent AVCs.